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Self-heating and self-ignition in dairy powders

机译:奶粉中的自热和自燃

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摘要

Self-heating in dairy powders is a cause of fires and explosions in processing equipment and storage facilities in the dairy industry. Prevention offers the best method of limiting the occurrence. Thus, prediction of the conditions which are conducive to the commencement and propagation of heating in milk powders is essential.;A finite element model was developed to simulate self-heating of a sphere of powder for variable environmental and product conditions including finite surface and internal resistance to heat transfer. The solution is accurate and stable over the range of parameters and properties likely to be encountered commercially.;The Differential Scanning Calorimeter (DSC) provided kinetic data for the model which was subsequently validated by predicting the Minimum Ignition Temperature (MIT) of the milk powder under the test conditions. In the experiments commercial powders were subjected to a high-temperature environment in a standard oven and MIT values determined. Experimental inaccuracies in the DSC resulted in simulated MIT values averaging 13% above the experimental results.;The model was further employed to estimate the MIT values using the oven-derived kinetic data. Thus, for a 2$sp{primeprime}$ sphere of skim-milk powder, the oven predicts an MIT of 161$spcirc$C, compared to a predicted MODEL/OVEN value of 159$spcirc$C, and a MODEL/DSC value of 179$spcirc$C. The model specifically identifies the lowest ambient temperature at which ignition occurs, giving a better combustion indicator than the traditional 'MIT'.;Experimental and simulation results show that the TtI (Time to Ignition) increases as the sphere radius increases. The TtI decreases exponentially when the ambient temperature increases linearly. The model predicts an exponential decrease in the TtI for a linear decrease in the Activation Energy.;As a result of the findings, a number of specific practical recommendations are made regarding the prevention of self-heating/self-ignition in dairy powders.
机译:奶粉中的自热是导致奶业加工设备和存储设备着火和爆炸的原因。预防是限制发生的最佳方法。因此,预测有利于奶粉加热过程的开始和传播的条件是必不可少的。;建立了一个有限元模型来模拟在有限的环境和产品条件(包括有限的表面和内部)下奶粉球的自加热耐热传递。该解决方案在商业上可能遇到的参数和特性范围内是准确且稳定的。差示扫描量热仪(DSC)为模型提供了动力学数据,随后通过预测奶粉的最低点火温度(MIT)对其进行了验证。在测试条件下。在实验中,将商品粉末在标准烘箱中置于高温环境中,并确定MIT值。 DSC中的实验误差导致模拟MIT值平均比实验结果高13%。;进一步使用该模型使用烤箱衍生的动力学数据估算MIT值。因此,对于2 $ sp {primeprime} $的脱脂奶粉球体,烤箱的MIT预测值为161 $ spcirc $ C,而模型/烤箱的预测值为159 $ spcirc $ C,而模型/ DSC的预测值为价值179 $ spcirc $ C。该模型专门确定了发生点火的最低环境温度,从而提供了比传统“ MIT”更好的燃烧指标。实验和仿真结果表明,随着球体半径的增大,TtI(点火时间)也随之增加。当环境温度线性增加时,TtI呈指数下降。该模型预测了活化能的线性下降,TtI将呈指数下降。结果,针对预防奶粉中的自热/自燃,提出了许多具体的实用建议。

著录项

  • 作者

    O'Connor, James Finbarr.;

  • 作者单位

    Michigan State University.;

  • 授予单位 Michigan State University.;
  • 学科 Food science.;Agricultural engineering.
  • 学位 Ph.D.
  • 年度 1991
  • 页码 257 p.
  • 总页数 257
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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