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Microencapsulation effects on the electro-optical behavior of polymer cholesteric liquid crystal flakes.

机译:微囊化对聚合物胆甾型液晶薄片的电光行为的影响。

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摘要

A modeling method is introduced for predicting the effect of microencapsulation on the electro-optical behavior of polymer cholesteric liquid crystal (PCLC) flakes suspended in a host fluid. The electric field acting on the flakes is significantly altered as various materials and boundary conditions are explored. The modeling predicts that test cells with multiple materials in the electric field path can have a wide range of electro-optic responses in AC electric fields. For DC drive conditions at high field strengths and test cell materials with low dielectric constants, electrophoretic behavior is observed for PCLC flakes. Prototype test cells for several encapsulation configurations are characterized for their resulting electro-optical behavior. The observed flake motions are in good agreement with the predicted results. This modeling method is shown to be a useful predictive tool for developing switchable particle devices utilizing microencapsulated dielectric particles in a host fluid medium.;This work further builds on previous research on flake motion in a host fluid suspension, exploring flake doping effects, both internal and surface coated. Host fluids were also doped for increased conductivity and are explored for their effect on PCLC flake motion. A low dielectric property host fluid doped with an aqueous salt solution and a surfactant is found to enable Maxwell-Wagner reorientation in a DC electric field. In an AC electric field the doped host fluid is found to have dual-frequency response enabling a reverse drive for PCLC flakes. Below the turnover frequency, flakes align parallel to the electric field and above the turnover frequency the flakes align perpendicular.
机译:引入了一种建模方法来预测微囊化对悬浮在宿主流体中的聚合物胆甾型液晶(PCLC)薄片的电光行为的影响。随着各种材料和边界条件的探索,作用在薄片上的电场发生了显着变化。该模型预测,电场路径中具有多种材料的测试单元在交流电场中可能具有广泛的电光响应。对于高场强下的直流驱动条件和介电常数低的测试电池材料,PCLC薄片的电泳行为被观察到。针对几种封装配置的原型测试电池的特征在于其产生的光电行为。观察到的薄片运动与预测结果非常吻合。该建模方法被证明是使用宿主流体介质中的微囊化电介质颗粒开发可切换颗粒装置的有用预测工具;该工作进一步建立在先前对宿主流体悬浮液中薄片运动的研究基础上,探索了薄片掺杂效应,包括内部和表面涂层。还掺杂了主机液以提高电导率,并探讨了它们对PCLC薄片运动的影响。发现掺有盐水溶液和表面活性剂的低介电特性主体流体能够在直流电场中实现麦克斯韦-瓦格纳重取向。在交流电场中,发现掺杂的主流体具有双频响应,从而可以反向驱动PCLC薄片。在周转频率以下,薄片平行于电场排列,而在周转频率以上,薄片垂直排列。

著录项

  • 作者

    Cox, Gerald Philip.;

  • 作者单位

    University of Rochester.;

  • 授予单位 University of Rochester.;
  • 学科 Engineering Electronics and Electrical.;Engineering Materials Science.;Physics Optics.
  • 学位 Ph.D.
  • 年度 2009
  • 页码 276 p.
  • 总页数 276
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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