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Volcanic Glass as a Paleoenvironmental Proxy: Comparing Preparation Methods on Ashes from the Lee of the Cascade Range in Oregon, USA

机译:火山玻璃作为古环境的代用品:美国俄勒冈州喀斯喀特山脉李氏火山灰的制备方法比较

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摘要

Deuterium ratios (deltaD) of hydrated volcanic glass have been used to reconstruct paleoenvironments, although the reliability and proper sample preparation protocol have been debated. In this study, hydrated volcanic ash samples from the lee of the Cascades were prepared using two separate methods. Method 1 involves sonicating and rinsing samples with hydrochloric acid (HCl) followed by hand-selection of glass shards (125 --212microm). Method 2 requires hydrochloric acid (HCl) and hydrofluoric acid (HF) abrasion as well as heavy liquid separation of shards (70 --150microm). Method 2 produced more consistent results with decreased intra-replicate variability in both water content (-0.92 wt. %) and deuterium values (-2.5‰ deltaD). Method 2 deltaD values of ≥ 99% isotropic glass were also 2.5 -- 10 ‰ more negative relative to Method 1 values, with an increasing discrepancy with age (3.68 -- 32.66 Ma). Method 2 results suggest volcanic glass did not re-equilibrate with modern water, based on 1) < 2‰ discrepancies between samples of the same ash flow taken from unique sample localities and 2) a ~20‰ difference between samples of different ages (~8 Ma apart) from the same locality. These results support the specified use of HF abrasion and heavy liquid separation on 70 -- 150 microm glass shards to minimize the impact of contaminants on reconstructed paleowater deltaD values.
机译:尽管已经讨论了可靠性和适当的样品制备方案,但水合火山玻璃的氘比(deltaD)已用于重建古环境。在这项研究中,使用两种不同的方法制备了从喀斯喀特山脉中风的水合火山灰样品。方法1涉及用盐酸(HCl)进行超声处理和冲洗,然后手动选择玻璃碎片(125 --212微米)。方法2需要盐酸(HCl)和氢氟酸(HF)的磨损以及碎片的重液分离(70 --150microm)。方法2产生了更一致的结果,同时降低了含水量(-0.92 wt。%)和氘值(-2.5‰deltaD)的复制内变异性。方法2的≥99%各向同性玻璃的delDD值也比方法1的负值多2.5-10‰,并且随着年龄的增长而增加(3.68-32.66 Ma)。方法2的结果表明,火山玻璃没有用现代水重新平衡,原因是基于1)从唯一的样本位置获取的相同灰分流样本之间的差异小于2‰,以及2)不同年龄的样本之间存在〜20‰的差异(〜相距8 Ma)。这些结果支持在70-150微米玻璃碎片上使用HF研磨和重液分离的特定用途,以最大程度地减少污染物对重建的古水δD值的影响。

著录项

  • 作者

    Carlson, Tessa Boe.;

  • 作者单位

    Portland State University.;

  • 授予单位 Portland State University.;
  • 学科 Geochemistry.
  • 学位 M.S.
  • 年度 2018
  • 页码 105 p.
  • 总页数 105
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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