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Coupling geochemistry and real-time water quality sensing for identifying and quantifying basin brine and road salt sources in watersheds along the New York Pennsylvania border.

机译:耦合地球化学和实时水质感测,以识别和量化纽约宾夕法尼亚州边界流域中的盆地盐水和道路盐分来源。

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摘要

The following chapters explore coupled geological and hydrological tracers which can be used to identify basin brine and road salt sources in surface and ground waters in watersheds along the New York and Pennsylvania border. They attempt to further our understanding of geochemical fingerprints which can be used to identify and quantify sources, as well as to characterize regional baseline conditions prior to development of natural gas resources from the Marcellus Shale using horizontal drilling techniques. In chapter one, Cl/Br and (Ba+Sr)/Mg ratios were used to distinguish between brine sources in streams, and when integrated with groundwater sampling results, indicate pre-existing high total dissolved solids (TDS) sources are prevalent throughout the Upper Susquehanna River Basin. Chapter two identifies several geochemical fingerprints which can be used to identify the Marcellus Shale in comparison to surrounding units from drill cutting waste disposal perspectives. Based on results from water/rock interaction experiments, Pb isotope ratios, Mo, and other trace metals can be used as diagnostic fingerprints for leachate generated from the Marcellus Shale. In chapter three, real-time stream conductivity data was used to detect high TDS inputs into surface water from basin brine and road salt sources. Short and long term perturbations in conductivity from these sources are distinguishable in relation to baseline conditions, and prediction of sonde conductance response to pollutant loading scenarios can be modeled. These chapters indicate that hydrological and geochemical metrics can be used by water resource professionals to characterize sources and water quality conditions pre and post horizontal natural gas drilling in watersheds on local and regional scales.
机译:以下各章探讨了地质和水文耦合示踪剂,可用于识别纽约和宾夕法尼亚边界沿流域的地表水和地下水中的盆地盐水和道路盐分源。他们试图加深我们对地球化学指纹的理解,这些指纹可用于识别和量化来源,以及在使用水平钻井技术从马塞勒斯页岩开发天然气资源之前表征区域基线条件。在第一章中,使用Cl / Br和(Ba + Sr)/ Mg之比来区分溪流中的盐水源,并将其与地下水采样结果结合起来,表明整个过程中普遍存在预先存在的高总溶解固体(TDS)源。上萨斯奎哈纳河流域。第二章从钻屑处理的角度出发,鉴定了几种地球化学指纹,与周围的单元相比,可以用来鉴定马塞勒斯页岩。根据水/岩相互作用实验的结果,Pb同位素比,Mo和其他痕量金属可用作Marcellus页岩产生渗滤液的诊断指纹。在第三章中,使用实时流电导率数据检测流域盐水和道路盐源向地表水中输入的高TDS。与基线条件相比,来自这些来源的电导率的短期和长期扰动是可区分的,并且可以对探空仪电导率对污染物负荷情况的响应进行建模。这些章节表明,水资源专业人士可以使用水文和地球化学指标来表征局部和区域尺度上流域水平天然气钻井前后的水源和水质状况。

著录项

  • 作者

    Johnson, Jason D.;

  • 作者单位

    State University of New York at Binghamton.;

  • 授予单位 State University of New York at Binghamton.;
  • 学科 Geochemistry.;Engineering Environmental.;Hydrology.
  • 学位 Ph.D.
  • 年度 2014
  • 页码 147 p.
  • 总页数 147
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 水产、渔业;
  • 关键词

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