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Oxidation of Dibenzothiophene to Dibenzothiophene-Sufone Using a Molybdenum (VI) Oxide Catalyst: A Kinetic Study Testing Solvent Dependency and Mole Ratio Efficiency

机译：使用氧化钼（VI）催化剂将二苯并噻吩氧化为二苯并噻吩-砜：测试溶剂依赖性和摩尔比效率的动力学研究

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Oxidative desulfurization (ODS) is currently a solution to hydrodesulphurization. Currently, industrial usage of hydrodesulphurization (HDS) is the common source for petroleum purification. Unfortunately, HDS comes with environmental and economical ramifications. Due to the problems and potential hazards being presented with HDS, ODS has become a topic of interest in research development. A kinetic study using molybdenum (VI) oxide as a catatyst was used in oxidative desulfurization. Factors such as mole ratio and solvent dependency were tested for efficiency. As activation energy was calculated to show maximum efficiency with respect to temperature and concentration. Gas Chromatography, FT-IR, and Mass Spectroscopy were used to characterize dibenzothiophene-sulfone.

机译：氧化脱硫（ODS）当前是加氢脱硫的解决方案。当前，加氢脱硫（HDS）的工业用途是石油提纯的常见来源。不幸的是，HDS带来了环境和经济方面的影响。由于HDS带来的问题和潜在危害，ODS已成为研究开发中的关注话题。使用氧化钼（VI）作为催化剂的动力学研究用于氧化脱硫。测试了诸如摩尔比和溶剂依赖性的因素的效率。计算活化能以显示相对于温度和浓度的最大效率。气相色谱，傅立叶变换红外光谱和质谱用于表征二苯并噻吩砜。

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作者
Trevino, Tomas, Jr.;
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作者单位

The University of Texas Rio Grande Valley.;

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授予单位 The University of Texas Rio Grande Valley.;
学科 Chemistry.
学位 M.S.
年度 2017
页码 58 p.
总页数 58
原文格式 PDF
正文语种 eng
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Oxidation of Dibenzothiophene to Dibenzothiophene-Sufone Using a Molybdenum (VI) Oxide Catalyst: A Kinetic Study Testing Solvent Dependency and Mole Ratio Efficiency

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