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>Off-axis cavity ring down spectroscopy with exponential and phase shift detection: Absorption spectra of weak transitions at low temperatures.
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Off-axis cavity ring down spectroscopy with exponential and phase shift detection: Absorption spectra of weak transitions at low temperatures.
In this dissertation the ability of the off-axis laser injection in cavity ring down experiments is shown. Modulated continuous wave and pulsed lasers are used to obtain the absorption spectra of weak transitions at low temperatures. The absorption spectra of the red atmospheric bands of O2 (A-band and gamma-band), the overtone (Deltaupsilon =4) band of HD and the C-H (Deltaupsilon = 4, 5 and 6) overtone spectra of polyatomic molecules (C2H6, CH2D 2, CHD3, C3H4, C6H 10 and C5SiH10) are presented. The integrated absorption of each band was calculated as a function of the density of the gas samples and used to obtain the band strength of these weak transitions. In addition, the Fourier-transform (IR and NIR) spectra between 2500 and 13000 cm-1 are presented for CH3D, CHD3, C 6H10 and C5SiH10. The local mode harmonic frequency and anharmonicity were obtained. The harmonically coupled anharmonic oscillator (HCAO) model was used to calculate energy levels and assign the absorption bands to particular transitions of CH3D, C6H1 0 and C5SiH10. Also, overtone intensities of CHD 3 were calculated using ab initio quantum mechanical methods and compared with the experimental data. Spectral simulations were performed in order to confirm the transitions and the temperature of the molecules in the cell. Lastly, photolysis of ethyl acetate via high vibrational overtone absorption is proposed.
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