茂金属催化剂具有高的立体选择性、催化活性等性能,目前是烯烃催化领域研究的热点.实验设计用茚分别与二苯甲酮、苯甲醛、丙酮、苯乙酮合成富烯,之后与处理过的二甲基咪唑结合形成配体.配体与前过渡金属Zr结合形成咪唑桥联单茂Zr配合物,并对该配合物的性能做出检测,结果表明,催化剂[2-[2-(η5-茚基)-2,2-二甲基乙基]-1H-咪唑]-二(N,N-二乙胺基)锆在110 ℃,Al/Zr比例为700:1时催化剂聚合苯乙烯的活性最高.%Metallocene catalyst is a research focus in the catalytic field of olefin so far for the outstanding performance of stereose-lectivity and catalytic activity.In this study,it was designed to obtain,firstly,fulvene generated using indene to react with diphenyl ketone,benzaldehyde,acetone,acetophenone,respectively;secondly,ligands was generated using obtained fulvene to react with pro-cessed dimethyl imidazole;lastly,imidazole was functionalized half-zirconocene complex generated using obtained dimethyl imidaz-ole to react with transition metal Zr.After the test on performance of the synthesized imidazole functionalized zirconocene complex, the result showed that activity of the catalyst[2-[2-(η5-indenyl)-2,2-dimethylethyl]-1H-imidazole]-2(N,N-diethylin)Zr reached the highest point when it was used to catalyze the styrene polymerization under reaction conditions of temperature 110 ℃ and ratio of Al/Zr 700 : 1.
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