用配体磺基水杨酸,1,10菲罗啉和CuCO3·Cu(OH)2·H2O反应合成了配合物[Cu3(hssal)2(phen)2(H2O)4]·2CH3OH(1)(H3hssal：磺基水杨酸；phen：1,10菲罗啉),用单晶X-射线衍射、元素分析和红外光谱对该配合物进行了表征。研究了1的固体荧光和热稳定性,并用它作为前驱体合成了CuO微晶粒子,用粉末XRD和SEM对合成的CuO进行了表征和形貌研究。%A new Cu(II)complex[Cu3(hssal)2(phen)2(H2O)4]·2CH3OH(1)(H3hssal:5-sulfosalicylic acid;phen:1,10-Phenanthroline)has been synthesized and characterized by single crystal X-ray diffraction,elemental analysis and FT-IR. Thermal stability and luminescent property of 1 are investigated. CuO microcrystal particles were produced by using powder sample of com-plex 1 as a precursor. The obtained CuO microcrystal is characterized and observed by XRD and SEM analyses.
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