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磁性石墨烯对结晶紫的吸附性能研究

         

摘要

The adsorptive property of crystal violet( CV) on graphene-based magnetic nanocomposite was studied,the effect of pH, concentration and temperature were analyzed. The resultant kinetic data were well fitted by a pseudo second-order model,the corre-lation coefficient(R2)was 0. 999. The adsorption isotherms for CV follow the Langmiur isotherm mode,Freundlich isotherm mode and D-R isotherm mode with R2 varying from 0. 970 to 0. 985. The Gibbs free energy was less than zero,and the equilibrium adsorp-tion capacity of the magnetic graphene increased with increasing the temperaure from 25℃ to 55℃,so that the adsorption process shoud be spontaneous and endothermic.%本文研究了磁性石墨烯对结晶紫的吸附特性,考察了pH、吸附剂用量、结晶紫浓度以及温度等对吸附平衡的影响。磁性石墨烯吸附结晶紫符合准二级动力学模型。不同温度下磁性石墨烯对结晶紫的吸附等温线满足Langmuir方程(R2>0.99)、Freundlich方程(R2>0.97)以及D-R模型(R2>0.96)。吸附热力学计算结果表明该吸附过程的△G<0,并且随着温度升高△G越来越小,表明该吸附反应是自发进行的吸热反应。

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