RuCl_3·3H_2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

SHAO Ming-bo1; LIU Gui-yan2; ZHAO Jing-jing1; WANG Xiao-yu1 and WANG Jian-hui1 1. Department of Chemistry; College of Science; Tianjin University; Tianjin 300072; P. R. China; 2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule; College of Chemistry; Tianjin Normal University; Tianjin 300387; P. R. China

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RuCl_3·3H_2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

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Herein lies a convenient and highly efficient method of olefin isomerization in the presence of RuCl3?3H2O in ionic liquid(IL). More importantly, RuCl3?3H2O is a robust and recyclable catalyst. Nine cycles of RuCl3?3H2O as the catalyst were performed for the isomerization reactions of the selected substrate in IL and MeOH.

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《高等学校化学研究：英文版》 |2012年第1期|67-69|共3页
作者
SHAO Ming-bo1; LIU Gui-yan2; ZHAO Jing-jing1; WANG Xiao-yu1 and WANG Jian-hui1 1. Department of Chemistry; College of Science; Tianjin University; Tianjin 300072; P. R. China; 2. Tianjin Key Laboratory of Structure and Performance for Functional Molecule; College of Chemistry; Tianjin Normal University; Tianjin 300387; P. R. China;
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中图分类硼有机化合物、铝有机化合物;电解质溶液理论;
关键词
异构化反应; 离子液体; 可回收; 烯烃; 钌; 系统; 介导; 催化剂;

机译：异构化反应;离子液体;可回收;烯烃;钌;系统;介导;催化剂;

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RuCl_3·3H_2O Mediated Olefin Isomerizations in Ionic Liquids: A Highly Recyclable System for Olefin Isomerizations

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