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《高等学校化学研究：英文版》
>Studies of Mixed-valence Compounds(Ⅰ)──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo_6O_(19)^(3-) in Aprotic Media
Studies of Mixed-valence Compounds(Ⅰ)──In-Situ FTIR and UV-Visible-Near-IR Spectroelectrochemical Studies of Mixed-valence Isopolyanion Mo_6O_(19)^(3-) in Aprotic Media
The mixed-valence isopolyanion Mo6O193- was investigated by means of cyclic voltammographic, in-situ FTIR and UV-Visible-Near-IR spectro-electrochemicalmethods in aprotic media. The experimental results indicate that the Mo6O193-was formed whereafter Mo6O193- was reduced, (E0’ = - 0. 690 V, n = 1 ). The characteristic absorptions of Mo6O193- are 500 nm, 900 nm and 1100 nm in UV-VisibleNear-IR spectrum and 940 cm-1 in IR spectrum.
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