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Flexible organic photovoltaic devices based on oligothiophene derivatives

         

摘要

For the purpose of developing flexible organic photovoltaic devices, we have fabricated two flexible devices using 5-formyl- 2,20:50,200:500,2000-quaterthiophene (4T-CHO), 5-formyl-2,20:50, 200:500,2000:5000,20000-quinquethiophene (5T-CHO) and 3,4,9,10-peryle- netertracarboxylic dianhydride (PTCDA). The PET-ITO/4T-CHO/PTCDA/Al device has an open circuit voltage (Voc) of 1.56 V, photoelectric conversion efficiency of 0.77%. The PET-ITO/5T-CHO/PTCDA/Al device has a Voc of 1.70 V, photoelectric conversion efficiency of 0.84%. The two flexible devices have high Voc (1.56 and 1.70 V). It is possible that intermolecular hydrogen bonding between-CHO group of nT-CHO and carboxylic dianhydride of PTCDA contributes to enhancing the efficiency by promoting interfacial electron transfer and eliminating the subconducting band trap sites.

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