1,2-环氧环己烷与2-环己烯-1-酮的等压汽液平衡

王学猛; 蒋登高; 耿再新

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1,2-环氧环己烷与2-环己烯-1-酮的等压汽液平衡

机译：1,2-环氧环己烷与2-环己烯-1-酮的等压汽液平衡

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Green oxidation of cyclohexene using dioxygen as oxidizing agent is highly desirable because of its environmental compatibility and economic impact. Separation of its oxidation products depends on the reliable vaporliquid equilibrium (VLE) data of relevant components, which are still lacking. The VLE data of binary system 1,2-epoxycyclohexane and 2-cyclohexen-1-one under ambient pressure were obtained using an improved VLE equipment EC-2 still in this work. The results showed that this bina system has no azeotropic point. Furthermore, the experimental VLE data were correlated with the Wilson thermodynamic model and the corresponding binary interaction parameters of the model were obtained. The results showed that the VLE data agreed well with the model and passed the thermodynamic consistency test of Herrington.

机译：利用二恶英作为氧化剂的环己烯的绿色氧化是非常理想的，因为其环境兼容性和经济影响。其氧化产物的分离取决于相关组分的可靠性蒸发物平衡（VLE）数据，仍然缺乏。使用改进的VLE设备EC-2在本工作中获得了在环境压力下的二元体系1,2-环氧环己烷和2-环己酮-1-α的VLE数据。结果表明，该Bina系统没有共沸点。此外，实验VLE数据与威尔逊热力学模型相关，并且获得了模型的相应二进制交互参数。结果表明，VLE数据与模型很好地同意，并通过了赫拉斯顿的热力学稠度试验。

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来源
《中国化学工程学报（英文版）》 |2009年第1期|136-139|共4页
作者
王学猛; 蒋登高; 耿再新;
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作者单位

School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;

School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;

School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;

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收录信息中国科学引文数据库(CSCD);中国科技论文与引文数据库(CSTPCD);
原文格式 PDF
正文语种 chi
中图分类化工过程（物理过程及物理化学过程）;
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1,2-环氧环己烷与2-环己烯-1-酮的等压汽液平衡

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