Syntheses and Crystal Structures of Na(H2O)(C17H13O6SO3)·2H2O and Ni(H2O)6(C17H13O6SO3)2·4H2O

ZHANG Zun-Ting张尊听; GUO Ya-Ning郭亚宁; LIU Qian-Guang刘谦光

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Syntheses and Crystal Structures of Na(H2O)(C17H13O6SO3)·2H2O and Ni(H2O)6(C17H13O6SO3)2·4H2O

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Two hydrates of sodium 5,7-dihydroxy-6,4'-dimethoxyisoflavone-3'-sulfonate ([Na(H2O)](C17H13O6SO3)·2H2O,thesized and characterized by IR, 1H NMR and X-ray diffraction analyses. The hydrate 1 crystallizes in the monoclinic system, space group P2(1) with a=0.8201(9) nm, b=0.8030(8) nm, c= 1.5361(16) nm,β= 102.052(12)°, V=0.9893(18) nm3, Dc= 1.579 g/cm3, Z=2,μ=0.252 nm-1, F(000)=488, R=0.0353, wR=0.0873. The hydrate 2belongs to triclinic system, space group P-1 with a=0.7411(3) nm, b=0.8333(3) nm, c=1.7448(7) nm, a=86.361(6)°, β= 86.389(5)°, y= 88.999(3)°, V= 1.0731(7) nm3, Dc= 1.587 g/cm3, Z= 1, μ=0.649 mm-1, F(000)=534. In the structure of 1, the sodium cation is coordinated by six oxygen atoms and two adjacent ones are bridged molecules in the structure of 2. Meanwhile, hydrogen bonds in two compounds, link themselves to assemble two three-dimensional network structures, respectively.

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《中国化学（英文版）》 |2004年第9期|971-977|共7页
作者
ZHANG Zun-Ting张尊听; GUO Ya-Ning郭亚宁; LIU Qian-Guang刘谦光;
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School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, Shaanxi 710062, China;

School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, Shaanxi 710062, China;

School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, Shaanxi 710062, China;

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irisolidon, sodium 5,7-dihydroxy-6,4'-dimethoxyisofiavone-3'-sulfonate, nickel 5,7-dihydroxy-6,4'-dimethoxyisoflavone-3'-sulfonate, crystal structure, C-H…π, hydrogen bond;

机译：鸢尾碱;5,7-二羟基-6,4'-二甲氧基异黄酮-3'-磺酸钠;5,7-二羟基-6,4'-二甲氧基异黄酮-3'-磺酸镍;晶体结构;C-H…π;氢键;

Syntheses and Crystal Structures of Na(H2O)(C17H13O6SO3)·2H2O and Ni(H2O)6(C17H13O6SO3)2·4H2O

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