Generation of carbon-metal species is extremely important in transition metal-catalyzed organic synthesis.Among the various methods,1,4-metal migration is a very useful way to create new carbon-metal species,which are not readily accessible via classic methods.This review summarized recent advances in transition metal-catalyzed reactions,which involved one or more steps of 1,4-metal migration.It focused mostly on the achievements in Pd and Rh-catalyzed reactions,along with some of the remarkable results in Pt,Ir,Co,Fe-involved transformations.
展开▼
