A cyano-bridged heterometallic supramolecular complex{[Cu(pn)]3[Ni(CN)4]3}n(1)has been synthesized and structurally characterized by single crystal X-ray diffraction.1 displays an interesting 3D structure formed by μ4,μ3-[Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(Ⅱ)ions.The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(Ⅱ)ions through the diamagnetic spacer NC-Ni-CN.CCDC:624387.
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