2-羟基萘甲醛苯甲酰腙(H2L)由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得.利用H2L分别合成了钼和钒的配合物,[MoO2(EtOH)L](1)和[VO(OMe)L(MeOH)](2),并测定了它们的晶体结构.配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位构型.%The new aroyl-hydrazone ligand, 2-Hydroxy naphthaldehyde benzoylhydrazone (H2L), was prepared by the reaction of 2-Hydroxy naphthaldehyde and benzoyhydrazine in an ethanol solution. Two complexes, [MoO2(EtOH)L](1) and [VO(OMe)L(MeOH)](2), based on the H2L ligand have been synthesized and characterized by single crystal X-ray diffraction analysis. Complexes 1 and 2 exhibit analogous structural units, the metal atom in which has a distorted octahedral coordination geometry. CCDC: 298811 (1), 298810 (2).
展开▼
