The reaction of homochiral bis(2-isopropyl-5-methylcyclohexyl xanthalato) nickel(Ⅱ) with pyridine yields an chiral adduct bis(2-isopropyl-5-methylcyclohexyl xanthalato)(dipyridine) nickel(Ⅱ) ( Ⅰ ) in which the coordination geometry of the central Ni atom displays a slightly distorted octahedron composed of four S atoms from two xanthalato ligands and two N atoms from pyridine rings. CCDC: 252342.
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机译:前所未有的双核二硫代氨基甲酸镉加合物:双μ2-N-(2-羟基乙基基)-N-异丙基氨基甲酸氨基硫代氨基甲酸-κ3S:SS bis {N-(2-羟基乙基基)-N-异丙基氨基甲酰胺基硫基-κ2SS(3-{((1E)-(E)-2-(吡啶-3-基甲基亚叉基)肼一-1-基叉基甲基基}吡啶-κN)镉二水合物