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Alkali desilicated coal fly ash as substitute of bauxite in lime-soda sintering process for aluminum production

机译:碱脱硅粉煤灰替代铝土矿生产中石灰-苏打烧结工艺中的铝土矿

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摘要

By desilication treatment,the Al2O3/SiO2 molar ratio of coal fly ash could be improved to the range of 1.63-2.0.The desilicated coal fly ash(DSCFA)was enriched in alumina extraction.A processing technology was developed for alumina extraction from the DSCFA with the lime sintering process.Ca/(SiO2+TiO2)molar ratio,and NaO/Al2O3 molar ratio,sintering time,and temperature were the most significant parameters impacting on the aluminum extraction efficiency.The optima aluminum extraction efficiency was obtained under conditions of Ca/(SiO2+TiO2)molar ratio of 2.0,NaO/Al2O3 molar ratio of 0.98,and sintering at 1 200 ℃for 60 min.Astandard industrial dissolution method was used under conditions of caustic ratio(αk=n(NaO)/n(Al2O3)of 2.0,Al2O3 concentration of 50 g/L,sodium hydroxide concentration(Nk)of 60.78 g/L,Na2CO3 concentration of 10 g/L,temperature of 85℃, and dissolution duration of 10 min.The final aluminum extraction efficiency was 90%.
机译:通过脱硅处理,可以将粉煤灰的Al2O3 / SiO2摩尔比提高到1.63-2.0的范围。对脱硅粉煤灰(DSCFA)进行了氧化铝的富集。开发了一种从DSCFA中提取氧化铝的工艺技术Ca /(SiO2 + TiO2)摩尔比,NaO / Al2O3摩尔比,烧结时间和温度是影响铝提取效率的最重要参数。在以下条件下可获得最佳的铝提取效率: Ca /(SiO2 + TiO2)摩尔比为2.0,NaO / Al2O3摩尔比为0.98,在1200℃下烧结60分钟。在苛性比(αk= n(NaO)/ n (Al2O3)为2.0,Al2O3浓度为50 g / L,氢氧化钠浓度(Nk)为60.78 g / L,Na2CO3浓度为10 g / L,温度为85℃,溶解时间为10分钟。效率为90%。

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