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In situ polymerization preparation and characterization of Li4Ti5O12-polyaniline anode material

机译:Li4Ti5O12-聚苯胺负极材料的原位聚合制备与表征

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摘要

Li4Ti5O12 powders were prepared by so-gel method using tetrabutyl titanate,lithium acetate and absolute alcohol as starting materials.Li4Ti5O12-polyaniline(Li4Ti5O12-PAn)composite was prepared by in situ polymerization method using aniline, ammonium persulfate and hydrochloricarried as starting materials.Li4Ti5O12-PAn composite was characterized by X-ray diffractometry(XRD),infrared spectrum(IR)combined with electrochemical tests.The results show that the electrical conductivity is enhanced obviously due to the introduction of PAn to Li4Ti5O12.Li4Ti5O12-PAn composite exhibits better high-rate capability and cyclability than Li4Ti5O12.The composite can deliver a specific capacity of 191.3 and 148.9 mA·h/g,only 0.13%and 0.61%of the capacity is lose after being discharged 80 times at 0.1C and 2.0C,respectively.
机译:以钛酸四丁酯,醋酸锂和无水醇为原料,通过凝胶法制备Li4Ti5O12粉末;以苯胺,过硫酸铵和盐酸为原料,通过原位聚合法制备Li4Ti5O12-聚苯胺复合材料。通过X射线衍射(XRD),红外光谱(IR)结合电化学测试对-PAn复合材料进行了表征,结果表明,将PAn引入Li4Ti5O12中可以明显提高导电性。该复合材料可提供191.3和148.9 mA·h / g的比容量,分别在0.1C和2.0C放电80次后损失的容量仅为0.13%和0.61%。

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