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Recovery of oxalic acid from mother-liquor containing hydrochloric acid and cobalt by solvent extraction with P350

机译:P350溶剂萃取法从含盐酸和钴的母液中回收草酸

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摘要

The solvent of P350 was applied to extract and separate the oxalic acid from the mother-liquor originated from the precipitation of cobalt by oxalic acid,and its extraction mechanism was deduced.Some factors,including the concentration of P350, the concentration of hydrochloric acid and the concentration of oxalic acid were investigated to determine the best distribution coefficient of the oxalic acid.In the case of phase ratio(O/A)at 2.0,the extraction of the oxalic acid was more than 95%and its concentration in the extraction raffinate was lower than 0.004 0 mol/L after six-stage counter-current extraction.While the phase ratio(O/A)of the stripping was at 1.0,the recovery of oxalic acid attained more than 95%after ten-stage counter-current stripping.
机译:用P350的溶剂从草酸沉淀钴中分离出母液中的草酸,推导出其提取机理。研究草酸的浓度,确定草酸的最佳分配系数。在相比(O / A)为2.0的情况下,草酸的萃取率大于95%,且其在萃余液中的浓度大于95%。六阶段逆流萃取后,其低于0.004 0 mol / L。虽然汽提的相比(O / A)为1.0,但十阶段逆流后草酸的回收率达到95%以上剥离。

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