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Synthesis of ZnS nanoparticles by solid-liquid chemical reaction with ZnO and Na2S under ultrasonic

机译:超声作用下与ZnO和Na2S固液化学反应合成ZnS纳米粒子

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摘要

A novel and simple solid-liquid chemical reaction route was proposed to synthesize ZnS nanoparticles.In the method,ZnS nanoparticles were prepared by reaction of ZnO and Na2S in water with ultrasonic radiation at low temperature.The effects of process parameters on the properties of ZnS particles were investigated.The products were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM),transmission electron microscopy(TEM),infrared spectroscopy(IR),thermogravimetrydifferential thermogravimetry(TG-DTG)and fluorescence emission spectroscopy.The results show that these particles are good crystalline zinc blende with average size of 35 nm,and possess good IR transmittance in the range of 400 to 4 000 cm1and good thermal stability in oxygen.
机译:提出了一种新颖简单的固液化学反应路线来合成ZnS纳米粒子。该方法是通过ZnO和Na2S在水中与超声波辐射的低温反应制备的ZnS纳米粒子。工艺参数对ZnS性能的影响通过X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),红外光谱(IR),热重法,差示热重法(TG-DTG)和荧光发射光谱对产物进行表征。结果表明,这些颗粒为良好的结晶锌共混物,平均粒径为35 nm,在400至4000 cm1的范围内具有良好的红外透射率,并在氧气中具有良好的热稳定性。

著录项

  • 来源
    《中国有色金属学报:英文版》 |2010年第S1期|P.211-215|共5页
  • 作者

    佘媛媛; 杨娟; 丘克强;

  • 作者单位

    School of Chemistry and Chemical Engineering,Central South University;

    Hunan Chemical Industry Vocation and Technology Institute;

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  • 原文格式 PDF
  • 正文语种 CHI
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