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Synthesis and electrochemical performance of a novel nano sized Sn2SbNi composite

机译:新型纳米Sn2SbNi复合材料的合成与电化学性能

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摘要

Chemical reduction method was employed to prepare nano-sized Sn2SbNi alloy composites used as anode material for rechargeable lithium ion batteries.This strategy was adopted to combine the virtues of both active/inactive and active/active alloys to fabricate a Sn2SbNi alloy powder with two active components and one inactive component.The two active components can realize the high capacity feature of electrode and can make the volume change of electrode take place in a stepwise manner due to the different lithiation potentials of two active components,leading to a stable cycling performance.Sn2SbNi alloy provides a reversible specific capacity over 640 mA·h/g with an excellent cyclic ability.The Sn-Sb-Ni alloy composite material shows to be a good candidate anode material for the lithium ion batteries.
机译:采用化学还原法制备了可充电锂离子电池负极材料的纳米Sn2SbNi合金复合材料,结合活性/非活性和活性/活性合金的优点,制备了两种活性的Sn2SbNi合金粉末两种活性组分可以实现电极的高容量特性,并且由于两种活性组分的锂化电位不同,可以使电极的体积变化逐步发生,从而实现稳定的循环性能。 Sn2SbNi合金具有超过640 mA·h / g的可逆比容量,并且具有出色的循环能力。Sn-Sb-Ni合金复合材料是锂离子电池的理想负极材料。

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  • 来源
    《中国有色金属学报:英文版》 |2010年第S1期|P.253-256|共4页
  • 作者

    郭洪; 林雪飞; 陈益山;

  • 作者单位

    School of Chemical Science and Technology,Yunnan University;

    School of Chemistry and Chemical Engineering,Qujing Normal University;

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  • 正文语种 CHI
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