Four shapes of Cu2O particles as sphere,cube,truncated octahedron and octahedron were prepared via glucose reduction of Cu(Ⅱ)under alkaline condition.The products were characterized by XRD and SEM.The effects of the precursor(CuO,Cu(OH)2), reaction temperature and glucose concentration on morphology of Cu2O particles were investigated,and the mechanism of morphology control was discussed on the basic theory of crystal nucleation and growth.It is found that the Cu+supersaturation is remarkably influenced by the precursor kind,reaction temperature and glucose concentration,and the morphology of Cu2O particles can be controlled by the Cu+supersaturation.
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机译:在碱性条件下通过葡萄糖还原Cu(Ⅱ)制备了球形,立方体,截顶八面体和八面体四种形状的Cu2O颗粒。用XRD和SEM对产物进行表征。 ),研究了反应温度和葡萄糖浓度对Cu2O颗粒形貌的影响,并基于晶体成核和生长的基本理论探讨了形貌控制的机理。发现Cu +过饱和度受前驱物种类,反应的显着影响。 Cu +过饱和度可以控制温度和葡萄糖浓度,以及Cu2O颗粒的形貌。
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