Construction of Two Inorganic-organic Hybrid Vanadogermanates Based on Di-Cd-Substituted Ge-V-O Cluster and Transition-metal Complex Bridges

RU Jing-Jing; GU Ya-Nan; MA Xiang; CHEN Jian-Zhong; ZHENG Shou-Tian; LI Xin-Xiong

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Construction of Two Inorganic-organic Hybrid Vanadogermanates Based on Di-Cd-Substituted Ge-V-O Cluster and Transition-metal Complex Bridges

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Two new inorganic-organic hybrid vanadogermanates H[Cd(en)(phen)(H2O)]-[Cd(en)(phen)] { [Cd(phen)]2[Ge8V12O41(OH)7] }·5H2O (1) and[Cd(dien)2] [Cd(dien)]2 { [Cd(phen)]2-Ge8V12O42(H2O)(OH)6}·6.5H2O (2) (en =ethylenediamine,dien =diethylenetriamine,phen =1,10-phenanthroline) have been synthesized by hydrothermal method.Their structures were measured by single-crystal X-ray diffractions,thermogravimetric analysis,powder X-ray diffractions and infrared spectra.Structural analysis reveals that compound 1 is an infrequent dimeric structure based on di-Cd-substituted Ge-V-O cluster and transition-metal complex bridges,while compound 2 is an infinite 1-D chain constructed from di-Cd-substituted Ge-V-O clusters and dinuclear bridging complexes.Magnetic measurement indicated that both 1 and 2 exhibit antiferromagnetic behaviors.

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《结构化学》 |2018年第2期|219-229|共11页
作者
RU Jing-Jing; GU Ya-Nan; MA Xiang; CHEN Jian-Zhong; ZHENG Shou-Tian; LI Xin-Xiong;
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College of Chemistry, Fuzhou University, Fuzhou 350116, China;

Department of Chemistry, Ningde Normal University, Ningde, Fujian 352100, China;

College of Chemistry, Fuzhou University, Fuzhou 350116, China;

College of Chemistry, Fuzhou University, Fuzhou 350116, China;

College of Chemistry, Fuzhou University, Fuzhou 350116, China;

College of Chemistry, Fuzhou University, Fuzhou 350116, China;

College of Chemistry, Fuzhou University, Fuzhou 350116, China;

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Construction of Two Inorganic-organic Hybrid Vanadogermanates Based on Di-Cd-Substituted Ge-V-O Cluster and Transition-metal Complex Bridges

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