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首页> 中文期刊> 《结构化学》 >Syntheses, Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid

Syntheses, Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid

         
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摘要

Two coordination compounds, namely [Ce(3,5-Br2BC)3(3,5-HBr2BC)]n(1) and [Zn(3,5-Br2BC)2(phen)](2, 3,5-HBr2 BC = 3,5-dibromobenzoic acid, phen = 1,10-phenanthroline), were assembled. Single-crystal X-ray diffraction studies show that compound 1 possesses a 1D chain coordination network, which is further extended into a 3D supramolecular architecture via Br···Br and Br···O halogen bonding. Compound 2 consists of a mononuclear molecule, which is assembled to a 3D supramolecular framework through C–H···O hydrogen bond, π-π stacking interactions and Br···π halogen bonding. Luminescent and magnetic properties of both compounds have also been studied.

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  • 来源
    《结构化学》 |2015年第2期|227-234|共8页
  • 作者

    GAO Zhu-Qing; LI Hong-Jin; GU Jin-Zhong;

  • 作者单位

    School of Chemical and Biological Engineering,Taiyuan University of Science and Technology, Taiyuan 030021, China;

    School of Chemical and Biological Engineering,Taiyuan University of Science and Technology, Taiyuan 030021, China;

    College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;

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