首页> 中文期刊> 《结构化学》 >Two Three-dimensional Supramolecular Complexes Assembled by 2-Chlorinebenzoic Acid and Bis(imidazol) Ligands: Syntheses, Structures and Fluorescent Properties

Two Three-dimensional Supramolecular Complexes Assembled by 2-Chlorinebenzoic Acid and Bis(imidazol) Ligands: Syntheses, Structures and Fluorescent Properties

         

摘要

Two new three-dimemional supramolecular complexes,namely,[Cd(cba)2(bib)]n (1) and [Zn(cba)2(bib)]2n (2) (Hcba =2-chlorinebenzoic acid,bib =1,4-bis(imidazol-1-yl)-butane) were hydrothermally designed and synthesized.Their structures were determined by elemental analyses,IR spectroscopy,TG,fluorescence spectroscopy,single-crystal and powder X-ray diffraction.Complex 1 exhibits a one-dimensional zigzag chain and complex 2 shows a zero-dimensional structure,which were further extended into three-dimensional supramolecular structures through hydrogen bonds and π-π stacking interactions.

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  • 来源
    《结构化学》 |2018年第11期|1821-1828|共8页
  • 作者单位

    Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University);

    Ministry of Education;

    Changchun 130103;

    China;

    Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University);

    Ministry of Education;

    Changchun 130103;

    China;

    Faculty of Chemistry;

    Tonghua Normal University;

    Tonghua 134002;

    China;

    Faculty of Chemistry;

    Tonghua Normal University;

    Tonghua 134002;

    China;

    Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University);

    Ministry of Education;

    Changchun 130103;

    China;

    Key Laboratory of Preparation and Application of Environmental Friendly Materials(Jilin Normal University);

    Ministry of Education;

    Changchun 130103;

    China;

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  • 正文语种 eng
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