Hydrothermal Synthesis and Structure of One New Vanadoarsenate Zn(dien)(Hdien)2As6V15O42(H2O)·4H2O

ZHAO Dan; ZHENG Shou-Tian; YANG Guo-Yu

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Hydrothermal Synthesis and Structure of One New Vanadoarsenate Zn(dien)(Hdien)2As6V15O42(H2O)·4H2O

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One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, a = 13.959(3), b = 22.428(5), c = 22.831(5) , β = 90.733(4)o, Z = 4. X-ray crystallographic study showed that compound 1 is constructed from [As6V15O42(H2O)]6- polyoxoanions linked together by novel [Zn(dien)(Hdien)]3+ complex fragments via hydrogen bonds into a three-dimensional network. Variable temperature susceptibility measurement demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.

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《结构化学》 |2009年第4期|503-508|共6页
作者
ZHAO Dan; ZHENG Shou-Tian; YANG Guo-Yu;
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State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China;

Biology and Chemistry Engineering Department of Fuqing Branch of Fujian Normal University Fuqin Branch of Fujian Normal University Fuqing Fujian 350300 China;

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1. Hydrothermal Synthesis and Structure of One New Vanadoarsenate Zn（dien）（Hdien）2As6V15O42（H2O）·4H2O [J] . ZHAO Dan ,ZHENG Shou-Tian ,YANG Guo-Yu . 结构化学 . 2009,第004期
2. Synthesis, Crystal Structure and Luminescence of a New Zn(Ⅱ) Dimer: Zn(bpdc)(L)2·4H2O [J] . WANG Xiu-Yan ,LIU Fu-Yi ,KONG De-Yu . 结构化学 . 2014,第010期
3. Hydrothermal Synthesis and Crystal Structure of a Hybrid Compound Based on β-Octamolybdate Mn(2,2'-bipy)32β-Mo8O26·4H2O [J] . . 结构化学 . 2005,第010期
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6. FeCl2·4H2O流态化煅烧过程及动力学研究 [A] . 王玲 . 2017

Hydrothermal Synthesis and Structure of One New Vanadoarsenate Zn(dien)(Hdien)2As6V15O42(H2O)·4H2O

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