We construct an atomic group model of the disordered binary alloy Nix-Cu1-x for the cases that the surface composition segregation exists or not. According the model, we calculate the electronic structure in a top site of Nix-Cu1-x alloy surface by using the recursion method when CO absorbed on the Nix-Cu1-x surface under the condition of coverage 0.5. The calculation result indicates that chemical absorption of CO reduces the density of states of the disordered binary alloy Nix-Cu1-x, widens the energy band, and strengthens the covalent bonds between the d electron of Ni and s or p electron of CO. Chemisorption of CO inhibits the enrichment of atom Cu on the alloy surface especially when bulk Ni Concentration x is less than 0.8.
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机译:Total maximum Daily Loads of Nitrogen for Three Tidal Tributaries and Total maximum Daily Load of Biochemical Oxygen Demand for One Tributary in the Newport Bay system, Worcester County, maryland.