首页> 中文期刊> 《中国物理快报:英文版》 >In Situ Raman Spectroscopy Study on Dissociation of Methane at High Temperatures and at High Pressures

In Situ Raman Spectroscopy Study on Dissociation of Methane at High Temperatures and at High Pressures

         

摘要

We investigate the stability and dissociation of methane,which is the most abundant organic molecule in the universe,using diamond anvil cell(DAC)with in situ Raman spectroscopy up to 903K and 21GPa.At the temperatures of 793 and 723K and the corresponding pressures of 16.15 and 20.30 GPa,methane dissociates to very high,methane remains stability up to the highest temperature of 903 K of the work.The four symmetricC-H bonds of methane split at high temperatures and at high pressures,and there is at least one phase transitionof crystalline symmetry from face centred cubic (fce) to hexagonal dose packed (hcp) before dissociation.

著录项

  • 来源
    《中国物理快报:英文版》 |2008年第2期|780-782|共3页
  • 作者单位

    School of Environmental and Chemical Engineering,Shanghai University,Shanghai,201800;

    School of Environmental and Chemical Engineering,Shanghai University,Shanghai,201800;

    School of Sciences,Shanghai University,Shanghai,200436;

    School of the Earth and Space Sciences,Peking University,Beijing,100871;

  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类 物理学;
  • 关键词

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