New family of single-component Ni catalysts for ethylene polymerization to high and ultrahigh molecular weight polyethylene

Artem A.Antonov; Wen-Hua Sun; Konstantin P.Bryliakov

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New family of single-component Ni catalysts for ethylene polymerization to high and ultrahigh molecular weight polyethylene

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Since the milestone discovery of Ni(II)salicylaldiminate catalysts by Grubbs and co-workers[1],nickel(II)complexes with N,N-and N,O-donor ligands have strengthened their lead in the search for highly active platforms for olefins homo-and copolymerization with various co-monomers,including those with polar groups,to achieve polymers with precisely controlled microstructures[2,3].

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《中国科学》 |2020年第6期|P.753-754|共2页
作者
Artem A.Antonov; Wen-Hua Sun; Konstantin P.Bryliakov;
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作者单位

Boreskov Institute of Catalysis Pr.Lavrentieva 5 Novosibirsk 630090 RussiaNovosibirsk State University Pirogova 1 Novosibirsk 630090 Russia;

Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100190 ChinaCAS Research/Education Center for Excellence in Molecular Sciences University of Chinese Academy of Sciences Beijing 100049 China;

Boreskov Institute of Catalysis Pr.Lavrentieva 5 Novosibirsk 630090 RussiaNovosibirsk State University Pirogova 1 Novosibirsk 630090 Russia;

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原文格式 PDF
正文语种 chi
中图分类 TQ325.12;
关键词
discovery; catalysts; co-monomers;

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New family of single-component Ni catalysts for ethylene polymerization to high and ultrahigh molecular weight polyethylene

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