Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups

Makoto Minato; Chiharu Sorai; Takashi Ito; Masashi Kiguchi; Midori Kato

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Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups

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Much interest has been devoted to organometallic NLO materials. We have become interested in exploring the utility of ferrocenyl group as the conjugating bridge. Thus, we synthesized 1-{{[1,3-(5-methylbenzo)dithiol]-2-yli- dene}methyl}-1’-[2-(p-nitrophenyl)-(E)-ethenyl]ferrocene (1). This new ferrocenyl compound has a donor and an acceptor group in 1,1’-positions. Investigations of the solvatochromic property of the compound revealed that it has polarized structure in a polar solvent, such as DMF. SHG efficiency of the compound was estimated by an SHEW (second-harmonic generation with the evanescent wave) method.

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《有机化学国际期刊（英文）》 |2017年第3期|284-294|共11页
作者
Makoto Minato; Chiharu Sorai; Takashi Ito; Masashi Kiguchi; Midori Kato;
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作者单位

Department of Materials Chemistry;

Faculty of Engineering;

Yokohama National University;

Yokohama;

Japan;

Advanced Research Laboratory;

Hitachi Ltd.;

Hatoyama;

Japan;

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原文格式 PDF
正文语种 chi
中图分类化学;
关键词
Nonlinear; Optical; Material; Ferrocenyl; Derivative; Solvatochromic; Property; SHG; Efficiency;

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Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups

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