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《材料科学与化学工程（英文）》
>Study on the Mechanism of Heterogeneous Catalysis (1) —The Measurement of Equilibrium Pressure of Reaction BaCOsub3/sub+ C = BaO + 2CO, the Chemical States of Fe in Reaction Tank, and Chemical Reaction Model Catalytic Cycle Mechanism (CRMM)
Study on the Mechanism of Heterogeneous Catalysis (1) —The Measurement of Equilibrium Pressure of Reaction BaCOsub3/sub+ C = BaO + 2CO, the Chemical States of Fe in Reaction Tank, and Chemical Reaction Model Catalytic Cycle Mechanism (CRMM)
The results on the equilibrium pressure measurement of BaCO3 + C = BaO + 2CO reaction and the demonstration of chemical state of iron proved that decomposition-generation cycle of BaCO3 and oxidation-reduction cycle of Fe in that reaction condition case were impossible to occur. The Chemical Reaction Model Catalytic Cycle Mechanism-CRMM does not exist at all for BaCO3, Fe, Noble metal catalysts. To call CRMM as a “principle” was obviously inappropriate. The TOF (Turnover Frequency—TOF: unit: s-1) was used to measure the activity size and life of catalyst, and it is clearly out of nothing.
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