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Effects of magnetic ionic liquid as a lubricant on the friction and wear behavior of a steel-steel sliding contact under elevated temperatures

         

摘要

A magnetic ionic liquid(abridged as MIL)[C_(6)mim]_(5)[Dy(SCN)_(8)]was prepared and used as the magnetic lubricant of a steel-steel sliding pair.The tribological properties of the as-prepared MIL were evaluated with a commercially obtained magnetic fluid lubricant(abridged as MF;the mixture of dioctyl sebacate and Fe_(3)O_(4),denoted as DIOS-Fe_3O_4)as a control.The lubrication mechanisms of the two types of magnetic lubricants were discussed in relation to worn surface analyses by SEM-EDS,XPS,and profilometry,as well as measurement of the electric contact resistance of the rubbed steel surfaces.The results revealed that the MIL exhibits better friction-reducing and antiwear performances than the as-received MF under varying test temperatures and loads.This is because the MIL participates in tribochemical reactions during the sliding process,and forms a boundary lubrication film composed of Dy_(2)O_(3),FeS,FeSO_(4),nitrogen-containing organics,and thioether on the rubbed disk surface,thereby reducing the friction and wear of the frictional pair.However,the MF is unable to form a lubricating film on the surface of the rubbed steel at 25°C,though it can form a boundary film consisting of Fe_(3)O_(4) and a small amount of organics under high temperature.Furthermore,the excessive Fe_(3)O_(4) particulates that accumulate in the sliding zone may lead to enhanced abrasive wear of the sliding pair.

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