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磷酸酯类阻燃剂在PC/ABS合金中的应用

         

摘要

In the paper, the flame-retardant properties, thermogravimetric analysis (TGA) and mechanical properties of PC/ABS with RDP, BDP and TPP as flame retardants were studied. The results showed that the limiting oxygen index (LOI) of PC/ABS was increased as the content of flame retardant increased, when the content of RDP or BDP was 15 wt%, the LOI were reached the maximum, 36.3 % and 35.5 % separately, and both reached FV-0 class. TGA analysis showed that the residue of flame-retarding PC/ABS was higher than neat PC/ABS, about 13 %. The results also showed the synergistic efficient of RDP/TPP or BDP/TPP were much better than RDP or BDP in flame-retardant properties.%文章研究了磷酸酯类阻燃剂RDP、BDP以及它们与TPP的协同作用对PC/ABS合金的阻燃性能、热失重行为以及力学性能的影响.结果表明,PC/ABS台金的LOI随着阻燃剂的增加而增加,当阻燃剂RDP和BDP添加量均为15%时,LOI达到最大值,分别为36.3%和35.3%,且均达FV-0级.通过热重分析表明,阻燃PC/ABS比纯PC/ABS合金的分解速率小得多.研究还表明,阻燃剂的协同作用使PC/ABS合金的阻燃性能优干添加单一阻燃剂的PC/ABS合金的阻燃性能.

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