A porous copper membrane was formed on the titanium flyer by the hydrogen bubble deposition, then porous copper azides was synthesized by in-situ synthesis method. Characterization and testing shows that, using hydrogen bubb-le template method can make a porous copper membrane with pore structure, and porous copper azides with about 20~100nm grain size was obtained using in-situ synthesis method, the thermal decomposition peak temperature of the product is 211.76℃, and the activation energy is 180kJ/mol. Through driving the titanium flyer by the porous copper azides, the CL-20 can be detonated.%采用氢气泡模版法，以金属钛飞片为电极，在飞片上直接沉积多孔铜膜，通过与叠氮酸气体之间的原位叠氮化反应生成多孔铜叠氮化物，对其形貌、热性能进行表征。结果表明：采用氢气泡模版法可制得具有三维多孔结构的多孔铜膜，原位叠氮化后的产物为叠氮化亚铜，叠氮化亚铜薄膜仍为多孔金属铜的三维孔状结构，晶粒尺寸约为20~100nm；叠氮化产物的热分解峰为211.76℃，活化能为180kJ/mol；采用制备的多孔铜叠氮化物驱动钛飞片，可引爆CL-20。
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