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首页> 中文期刊> 《农业科学学报（英文版）》 >Adsorption of Cu(II) on humic acids derived from different organic materials

Adsorption of Cu(II) on humic acids derived from different organic materials

         
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摘要

The adsorption of Cu(II) from aqueous solution onto humic acid (HA) which was isolated from cattle manure (CHA), peat (PHA), and leaf litter (LHA) as a function of contact time, pH, ion strength, and initial concentration was studied using the batch method. X-ray absorption spectroscopy (XAS) was used to examine the coordination environment of the Cu(II) adsorbed by HA at a molecular level. Moreover, the chemical compositions of the isolated HA were characterized by elemental analysis and solid-state13C nuclear magnetic resonance spectroscopy (NMR). The kinetic data showed that the adsorption equilibrium can be achieved within 8 h. The adsorption kinetics folowed the pseudo-second-order equation. The adsorption isotherms could be wel iftted by the Langmuir model, and the maximum adsorption capacities of Cu(II) on CHA, PHA, and LHA were 229.4, 210.4, and 197.7 mg g–1, respectively. The adsorption of Cu(II) on HA increased with the increase in pH from 2 to 7, and maintained a high level at pH>7. The adsorption of Cu(II) was also strongly inlfuenced by the low ionic strength of 0.01 to 0.2 mol L–1 NaNO3, but was weakly inlfuenced by high ionic strength of 0.4 to 1 mol L–1 NaNO3. The Cu(II) adsorption on HA may be mainly attributed to ion exchange and surface complexation. XAS results revealed that the binding site and oxidation state of Cu adsorbed on HA surface did not change at the initial Cu(II) concentrations of 15 to 40 mg L–1. For al the Cu(II) adsorption samples, each Cu atom was surrounded by 4 O/N atoms at a bond distance of 1.95 Å in the ifrst coordination shel. The presence of the higher Cu coordination shels proved that Cu(II) was adsorbedvia an inner-sphere covalent bond onto the HA surface. Among the three HA samples, the adsorption capacity and afifnity of CHA for Cu(II) was the greatest, folowed by that of PHA and LHA. Al the three HA samples exhibited similar types of elemental and functional groups, but different contents of elemental and functional groups. CHA contained larger proportions of methoxyl C, phenolic C and carbonyl C, and smaler proportions of alkyl C and carbohydrate C than PHA and LHA. The structural differences of the three HA samples are responsible for their distinct adsorption capacity and afifnity toward Cu(II). These results are important to achieve better understanding of the behavior of Cu(II) in soil and water bodies in the presence of organic materials.

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  • 来源
    《农业科学学报（英文版）》 |2015年第1期|168-178|共11页
  • 作者

    LI Cui-lan; JI Fan; WANG Shuai; ZHANG Jin-jing; GAO Qiang; WU Jing-gui; ZHAO Lan-po; WANG Li-chun; ZHENG Li-rong;

  • 作者单位

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Institute of Plant Science, Jilin Agricultural Science and Technology Colege, Jilin 132101, P.R.China;

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Colege of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, P.R.China;

    Institute of Agricultural Resources and Environments, Jilin Academy of Agricultural Sciences, Changchun 130124, P.R.China;

    Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, P.R.China;

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