首页> 中文期刊> 《粉末冶金材料科学与工程》 >HfC添加对钼钨合金高温等离子烧蚀性能影响及机理分析

HfC添加对钼钨合金高温等离子烧蚀性能影响及机理分析

         

摘要

本文通过等离子烧蚀系统结合扫描电子显微镜(SEM)研究掺杂不同量HfC颗粒对烧结态钼钨合金和轧制态钼钨合金烧蚀性能及烧蚀形貌的影响,同时探讨分析钼钨合金的高温烧蚀机理.结果表明无论是烧结态还是轧制态,HfC的添加都可以明显提高合金的抗烧蚀性能,且轧制态的抗烧蚀性能明显优于烧结态,因为经过轧制后,材料得到致密化,材料内的部分缺陷(如气孔、夹杂)被消除,同时材料内部颗粒由球形变为层片状,颗粒之间的结合力更强.与氧-乙炔烧蚀实验不同,等离子烧蚀实验过程由于使用保护气体,且焰流的冲击力较强,烧蚀过程主要是以热物理-机械剥离烧蚀为主,HfC 的掺杂机理主要是其本身具有的高熔点使其作为驻点存在,形成的少量HfO2覆盖在基体表面,对基体有一定的保护能力,使材料的高温性能得到提高.%The plasma ablation system combined with scanning electron microscopy (SEM) in this work were used to investigate the effects of different amounts of HfC particles on ablation performance and ablation morphology of sintered and rolled molybdenum-tungsten (Mo-W) alloys. Also, the high temperature ablation mechanism of the alloys was further discussed. The results show that the addition of HfC can significantly improve the ablation resistance of the alloys, including sintered and rolled alloys. The ablation resistance of the rolled alloys is obviously better than that of the sintered alloys due to the formation of lamellar structure and eliminating the internal defects (such as pores and impurity) after the rolled treatment. Compared with oxyacetylene ablation experiment, the plasma ablation experiment has protective gas along with strong impact force during ablation process. The ablation process is mainly physical and mechanical ablation. HfC doping mechanism is mainly because of its high melting point as a stagnation point. On the other hand, a small amount of HfO2 film formed on the substrate also has protection effect. As a result, high temperature ablation property of Mo-W alloys is increased.

著录项

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号