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Effects of Organic Acids on Adsorption of Cadmium onto Kaolinite, Goethite, and Bayerite

机译:有机酸对镉吸附在高岭石,针铁矿和拜耳石上的影响

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摘要

Effects of organic acids (oxalic, acetic, and citric) on adsorption characteristics of Cadmium (Cd) on soil clay minerals(kaolinite, goethite, and bayerite) were studied under different concentrations and different pH values. Although the types of organic acids and minerals were different, the effects of the organic acids on the adsorption of Cd on the minerals were similar, i.e., the amount of adsorbed Cd with an initial solution pH of 5.0 and initial Cd concentration of 35 mg L-1increased with increasing concentration of the organic acid in solution at lower concentrations, and decreased at higher concentrations. The percentage of Cd adsorbed on the minerals in the presence of the organic acids increased considerably with increasing pH of the solution. Meanwhile, different Cd adsorption in the presence of the organic acids, due to different properties on both organic acids and clay minerals, on kaolinite, goethite, or bayerite for different pHs or organic acid concentrations was found.
机译:研究了在不同浓度和不同pH值下,有机酸(草酸,乙酸和柠檬酸)对镉在土壤黏土矿物(高岭石,针铁矿和钙铝石)上的吸附特性的影响。尽管有机酸和矿物质的类型不同,但是有机酸对Cd在矿物质上的吸附的作用是相似的,即初始溶液pH为5.0和初始Cd浓度为35 mg L时吸附的Cd量。 -1在较低浓度时随溶液中有机酸浓度的增加而增加,而在较高浓度时则降低。在有机酸的存在下,吸附在矿物上的镉的百分比随着溶液pH值的增加而显着增加。同时,发现由于有机酸和粘土矿物,高岭石,针铁矿或钠铝石在不同pH或有机酸浓度下的性质不同,在有机酸存在下对镉的吸附不同。

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