首页> 中文期刊> 《石油炼制与化工》 >深度脱硫的渣油加氢处理RHT工艺研究

深度脱硫的渣油加氢处理RHT工艺研究

         

摘要

Hainan RDS feedstock and the third generation RHT series catalysts were used for stud-ying RHT process. The optimized catalyst grading and the calculated metal capacity of RHT graded cat-alysts were investigated. The process experiments were conducted using the best gradation of catalysts and the results indicated that to produce hydrotreated oil with sulfur content lower than 0. 20%,the volume space velocity is at least reduced to 0. 20 h-1. The stability test to produce hydrotreated oil with the sulfur con-tent lower than 0. 17% showed that using the optimized catalysts gradation and the appropriate process con-ditions(a partial pressure of hydrogen of 15. 0 MPa,a volume ratio of hydrogen to oil of 700,a volume space velocity of 0. 20 h-1 ),the average deactivation rate of third generation RHT series catalysts is 0. 082 ℃/d from 1000 h to 2000 h,which meets requirement for the long period operation.%采用中国石化海南炼油化工有限公司(简称海南炼化)渣油加氢(RDS)原料和第三代渣油加氢处理(RHT)系列催化剂开展了RHT工艺研究.通过催化剂的级配研究和RHT级配催化剂的容金属能力模拟计算,确定了优化的催化剂级配方案.采用优化的催化剂级配方案开展了工艺条件研究,结果表明,为了实现长周期稳定生产硫质量分数不大于0.20%的加氢生成油,海南炼化RDS装置体积空速应至少降低至0.20 h-1.稳定性试验结果表明,采用优化的催化剂级配方案和适宜的工艺条件(氢分压15.0 MPa,氢油体积比700,体积空速0.20 h-1),第三代RHT系列催化剂在1000~2000 h运转过程中的失活速率为0.082℃/d,可以满足工业装置长周期运转且稳定生产硫质量分数不大于0.17%的加氢生成油的要求.

著录项

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号