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一种超长链双子表面活性剂压裂液的性能评价

         

摘要

In order to enrich clean fracturing fluid systems in high temperature formations,a novel fracturing fluid was developed using cationic gemini surfactant (JS) as thickening agent and NH4Cl as counter-ion salt.JS which had a special structure consisting of ultra-long hydrophobic chains and amide groups,was synthesized using a main feedstock erucic acid obtained from rapeseed for thickening purposes.In this paper,the surface activity of JS and the formulation of JS/NH4Cl were investigated.And the performances of optimal formation of JS/NH4Cl such as temperature and shear tolerance properties,SEM and cryo-TEM morphology,viscoelasticity and fracturing properties were systematically evaluated.The results showed that JS had a low CMC value,and the optimum formulation of JS/NH4Cl system was 2.0% JS + 1.0% NH4Cl.The JS/NH4Cl system had good temperature and shear tolerance property,forming a three-dimensional network structure and exhibiting a strong viscoelastic characteristic.The JS/NH4Cl fluid could be broken automatically with oil and could be meet the fracturing requirements at 120 ℃.So,JS is a very promising candidate for fracturing.%为了丰富耐高温清洁压裂液体系,以来自于植物的芥酸为主要起始原料,嵌入酰胺基团,合成超长链双子表面活性剂(JS)作为稠化剂;并复合NH4Cl助剂配制清洁压裂液体系.考察了JS的表面活性;并对JS/NH4Cl体系进行配方优化.评价了优化体系的耐温耐剪切性、SEM和cryo-TEM形貌、黏弹性及压裂性能.结果表明:JS的CMC值低,优化的JS/NH4Cl体系配方为2.0% JS+1.0% NH4Cl,该体系耐温耐剪切性良好,可形成三维网状结构,呈现弹性流体性质,与油可自动破胶,能够满足120℃地层的压裂要求,具有良好的应用前景.

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