Based on the connotation of green supply chain,this paper establishes the supplier evaluation and selection model of core enterprises,and uses the ANP -TOPSIS method,at the same time with the aid of (SD)Super Decision software and MATLAB software to calculate and identify suitable suppliers.An example is given to evaluate the feasibility of the model.The results puts forward a kind of effective method for an enterprise to evaluate and select the supplier in green supply chain management.%根据绿色供应链管理的基本内涵建立核心企业绿色供应商的评价与选择模型，并应用 ANP －TOPSIS 的方法，同时借助（SD）Super Decision 软件以及 MATLAB 软件进行计算，评选出合适的供应商，最后结合案例验证了该方法的可行性，为绿色供应链视角下核心企业供应商的选择提供了一种科学有效的方法。
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