The optical properties of semiconductor nanocrystalline powder were studied by using photoacoustic spectroscopy technique. The band gap and the optical absorption coefficient of semiconductor nanocrystalline powder of TiO2, ZnO and Al-doped ZnO were measured by normalized photoacoustic spectroscopy technique The results show that the optical properties of semiconductor nanocrystalline powder relate to particle size and particle shape. The band gap and the optical absorption coefficient of semiconductor nanocrystalline powder can be controlled by its fabricating techniques. By doping and changing the size and the shape of nanocrystals, changing the optical and electrical properties was achieved.%应用新型的光声光谱技术,研究了不同种类和不同制备工艺条件的半导体纳米晶粉的光学特性,测量了半导体TiO2、ZnO和掺铝ZnO纳米晶粉的光声光谱,获得了这些半导体纳米晶粉的带隙和光谱吸收系数.研究结果表明,相同种类和相同颗粒形状的半导体纳米晶粉的粒径越小,光学吸收系数越大.半导体纳米晶粉的带隙与相同种类纳米颗粒形状(圆球形或棒形)密切相关.通过掺杂、改变粒径尺寸、改变形状可以达到改变纳米晶的光学、电学特性的目的.
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