Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy

Ahmed .I .El-Shenawy; Ishaq .F .E .Ahmed; Moamen .S .Refat

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Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy

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The main task of this article was to prepared of new pigment model in situ solar cells accordance to charge-transfer complexes of rhodamine C (RhC) donor as dye laser gain media with iodine (σ-acceptor) and chloranilic acid ,CLA (π-acceptor) .The synthesis stoichiometry of these complexes were of 1:2 (donor:ac-ceptor) with general formulas [(RhC)]I · I3 and [(RhC)(CLA)2 ] .The discussed data of elemental analysis , conductivity measurements ,FT-IR ,UV-Vis spectroscopy and photometric titration data visualized the stoichi-ometry ,formula and complexity of the complexes .The physicochemical and spectroscopic analyses obtained suggested that the electron transfer occurred through nitrogen atom in a tertiary amine —N (C2 H5 )2 of RhC donor with acceptor .The synthesized solid complexes were under go to thermogravimetric analyses to investi-gate their thermal stability and decomposition steps .The molar conductance measurements revealed that RhC complexes have an electrolytic statement .The thermal stability of rhodamine C complexes was enhanced in comparable with RhC itself .The polymer membranes of poly-methyl methacrylate) (PMMA) combined with the RhC charge(transfer complexes in chloroform solvent have been prepared and characterized by (infrared &electronic) spectroscopy and scanning electron microscopy (SEM) morphological examination .The photo-sta-bility properties of the RhC complexes have been investigated .

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《光谱学与光谱分析》 |2019年第7期|2307-2315|共9页
作者
Ahmed .I .El-Shenawy; Ishaq .F .E .Ahmed; Moamen .S .Refat;
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作者单位

Department of Chemistry;

Colloge of Education;

Imam Abdulrahman Bin Faisal University;

Dammam 1982;

Saudi Arabia;

Department of Chemistry;

Colloge of Education;

Imam Abdulrahman Bin Faisal University;

Dammam 1982;

Saudi Arabia;

Department of Chemistry;

Colloge of Education;

Imam Abdulrahman Bin Faisal University;

Dammam 1982;

Saudi Arabia;

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原文格式 PDF
正文语种 eng
中图分类半导体物理学;
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Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy

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