首页> 中文期刊> 《化工技术与开发》 >松节油体系组分饱和蒸气压研究进展

松节油体系组分饱和蒸气压研究进展

         

摘要

Research progress on saturated vapor pressure of turpentine components were summarized by reviewing the related literatures. According to the character which turpentine was composed of bicyclic monoterpene and bicyclic sesquiterpene, the principle, measurement, correlation and estimation method for determining saturated vapor pressure of turpentine components were presented. Turpentine components contained a variety of isomer with similar boiling point. Thus, pure turpentine components were hardly to obtain. Based on the regulation that the solvent in a dilute solution obeys Raoule’s law, the saturated vapor pressure data of pinane, cis-pinane, p-menthane and longifolene were measured indirectly. Good agreement of the correlated values was obtained when the experimental data of saturated vapor pressure and temperature were correlated by the three-parameter Antoine equation. In addition, the corresponding state group contribution-CSGC method was applied to estimation saturated vapor pressure for turpentine components.%本文综述了松节油体系组分的饱和蒸气压研究现状,根据松节油由双环单萜和倍半萜组成的特性,提出了适用于松节油体系组分饱和蒸气压的测定原理、测量方法、数据关联及估算方法。松节油体系组分是沸点相近的萜类同分异构体,难以分离得到纯度很高的松节油组分,利用稀溶液溶剂符合Raoult定律的原理,间接测定蒎烷、顺式蒎烷、对孟烷和长叶烯的饱和蒸气压。Antoine方程的三参数形式适用于松节油组分饱和蒸气压与温度的关联;对应态基团贡献法可应用于松节油组分饱和蒸气压数据的估算。

著录项

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号