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Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review

机译:基于将有机改性的过渡金属氧簇或多金属氧酸盐嵌入聚合物中以用于功能性应用的杂化材料:综述

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摘要

The covalent incorporation of inorganic building blocks into a polymer matrix to obtain stable and robust materials is a widely used concept in the field of organic-inorganic hybrid materials, and encompasses the use of different inorganic systems including (but not limited to) nanoparticles, mono- and polynuclear metal complexes and clusters, polyhedral oligomeric silsesquioxanes (POSS), polyoxometalates (POM), layered inorganic systems, inorganic fibers, and whiskers. In this paper, we will review the use of two particular kinds of structurally well-defined inorganic building blocks, namely transition metals oxoclusters (TMO) and polyoxometalates (POM), to obtain hybrid materials with enhanced functional (e.g., optical, dielectric, magnetic, catalytic) properties.
机译:将无机结构单元共价结合到聚合物基质中以获得稳定和坚固的材料是有机-无机杂化材料领域中广泛使用的概念,包括使用不同的无机体系,包括(但不限于)纳米颗粒,单分子-和多核金属络合物和簇,多面体低聚倍半硅氧烷(POSS),多金属氧酸盐(POM),层状无机体系,无机纤维和晶须。在本文中,我们将回顾两种在结构上明确定义的无机构建基块的使用,即过渡金属氧簇(TMO)和多金属氧酸盐(POM),以获得功能增强的混合材料(例如,光学,介电,磁性,催化)性能。

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