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Grain Boundary Character Dependence on Nucleation of Discontinuous Precipitates in Cu-Ti Alloys

机译:Cu-Ti合金中断续晶核形貌的晶界特征

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摘要

The dependence of the grain boundary character distribution for a Cu-4 at. % Ti polycrystal alloy (average grain size: 100 µm) on the nucleation of cellular discontinuous precipitates was systematically investigated. In an alloy over-aged at 723 K, cellular discontinuous precipitates consisted of a terminal Cu solid solution and a stable β-Cu4Ti lamellae nucleated at grain boundaries. Electron backscatter diffraction analysis revealed that the discontinuous precipitation reaction preferentially occurred at random grain boundaries with a Σ value of more than 21 according to the coincidence site lattice theory. On the other hand, few cellular discontinuous precipitates nucleated at low-angle and low-Σ boundaries, particularly twin (Σ 3) boundaries. These findings suggest that the nucleation of discontinuous precipitates is closely correlated with grain boundary character and structure, and hence energy and/or diffusibility. It should therefore be possible to suppress the discontinuous precipitation reaction through control of the alloy’s grain boundary energy, by means of texture control and third elemental addition.
机译:Cu-4 at的晶界特征分布的依赖性。对细胞不连续沉淀物成核的%Ti多晶合金(平均晶粒尺寸:100 µm)进行了系统研究。在723 K时效过时的合金中,蜂窝状不连续析出物由末端Cu固溶体和在晶界成核的稳定的β-Cu4Ti薄片组成。电子背散射衍射分析表明,根据重合点晶格理论,不连续沉淀反应优先发生在无规晶界,其Σ值大于21。另一方面,几乎没有细胞间断的沉淀物在低角度和低Σ边界处成核,尤其是孪生(Σ3)边界。这些发现表明,不连续析出物的形核与晶界特征和结构密切相关,因此与能量和/或扩散性密切相关。因此,应该可以通过组织控制和第三元素添加来控制合金的晶界能,从而抑制不连续的析出反应。

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