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Dye Degrading and Fouling-Resistant Membranes Formed by Deposition with Ternary Nanocomposites of N-Doped Graphene/TiO2/Activated Carbon

机译:N掺杂石墨烯/ TiO2 /活性炭三元纳米复合材料沉积形成的染料降解和防污膜

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摘要

A ternary nanocomposite consisting of N-doped graphene (NGR)/TiO2/activated carbon (NGRT@AC) was prepared, and the components’ synergetic effect on dye degradation was investigated after deposition on the surface of a polysulfone membrane (PSF). As far as we know, this ternary composite catalyst has never previously been used to degrade dyes nor been used as a functional layer for separation membranes. The surface morphology and structure of the as-prepared membranes were analyzed by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The NGRT@AC-modified PSF membrane (NGRT@AC-PSF) presents excellent photodegradation efficiency to methyl orange (MO) under both UV (95.2%) and sunlight (78.1%) irradiation, much higher than those values of PSF, TiO2- modified PSF (TiO2-PSF), and N-doped graphene/TiO2 (NGRT)-modified PSF membranes (NGRT-PSF) under the same conditions. The high flux recovery ratio (95.5%) demonstrates that the NGRT@AC-PSF membrane shows improved antifouling performance. The photocatalytic results prove that surface deposition method (95.2%) was better than the blending method (31.1%) for forming high-performance membranes. Therefore, the NGRT@AC-PSF membrane has the potential for broad applications in dye degradation to treat waste water from textile industries.
机译:制备了由N掺杂石墨烯(NGR)/ TiO2 /活性炭(NGRT @ AC)组成的三元纳米复合材料,并研究了其在聚砜膜(PSF)表面沉积后对染料降解的协同作用。据我们所知,这种三元复合催化剂以前从未被用于降解染料,也从未被用作分离膜的功能层。通过扫描电子显微镜(SEM)和能量色散X射线光谱(EDS)分析所制备膜的表面形态和结构。 NGRT @ AC改性的PSF膜(NGRT @ AC-PSF)在紫外线(95.2%)和阳光(78.1%)照射下均表现出优异的光降解为甲基橙(MO)的效率,远高于PSF,TiO2-的值改性PSF(TiO2-PSF)和N掺杂石墨烯/ TiO2(NGRT)改性PSF膜(NGRT-PSF)。高通量回收率(95.5%)证明NGRT @ AC-PSF膜具有改进的防污性能。光催化结果表明,表面沉积法(95.2%)比共混法(31.1%)更好地形成了高性能的膜。因此,NGRT @ AC-PSF膜在染料降解中具有广泛的应用潜力,可以处理纺织工业的废水。

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