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One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes with Sodium Perborate as the Oxidant†

机译：以碘化芳烃和芳烃为原料的一罐溴二芳基溴化铵制剂以过硼酸钠为氧化剂†

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This paper reports a one-pot synthesis of the title bromides from both activated and deactivated iodoarenes which are first oxidized with anhydrous NaBO3·H2O/Ac2O/conc.H2SO4 liquid mixtures, then coupled in situ with benzene and activated arenes and, finally, precipitated out with a KBr solution; this method is easy, cheap, safe and fairly effective.

机译：本文报道了从活化和失活的碘芳烃一锅法合成标题溴化物的方法，首先将其用无水NaBO3·H2O / Ac2O /浓H2SO4混合液氧化，然后与苯和活化的芳烃原位偶合，最后沉淀出来。推出KBr解决方案；这种方法简便，便宜，安全且相当有效。

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期刊名称 Molecules
作者
Anna Kryska; Lech Skulski;
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作者单位

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年(卷),期 2001(6),11
年度 2001
页码 875–880
总页数 6
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
diaryliodonium bromides iodoarenes arenes sodium perborate as oxidant;

机译：溴化二芳基碘鎓;碘芳烃;芳烃;过硼酸钠作氧化剂;

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专利

1. Unexpected,Drastic Effect of Triflic Acid on Oxidative Diacetoxylation of Iodoarenes by Sodium Perborate.A Facile and Efficient One-Pot Synthesis of (Diacetoxyiodo)arenes [J] . Md.Delwar Hossain, Tsugio Kitamura The Journal of Organic Chemistry . 2005,第17期

机译：三氟甲磺酸对过硼酸钠对碘芳烃的氧化二乙酰氧基化的出乎意料的剧烈影响。一种高效的一锅合成（Diacetoxyiodo）芳烃
2. Easy Preparation of (Diacetoxyiodo)arenes from Iodoarenes with Sodium Percarbonate as the Oxidant [J] . Agnieszka Zielinska, Lech Skulski Molecules . 2002,第11期

机译：以过碳酸钠为氧化剂从碘芳烃轻松制备（二乙酰氧基碘）芳烃
3. Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant† [J] . Lech Skulski Molecules . 2002,第11期

机译：以过碳酸钠为氧化剂，可从碘芳烃轻松制备[双（三氟乙酰氧基）碘]芳烃†
4. One-pot Synthesis of Arylbutadienes from Arenes and Ethyl Propiolate Using a Palladium Catalyst with Bidentate Phosphine Ligands [C] . Juzo Oyamada, Tsugio Kitamura Symposium on Organometallic Chemistry . 2007

机译：使用钯催化剂与二齿膦配体的钯催化剂合成芳基和乙酸乙酯的芳基丁合成
5. Synthesis and characterization of sol-gel-derived xerogel films with antifouling/foul release properties and the preparation, immobilization, and evaluation of a sequestered selenoxide catalyst for brominations with hydrogen peroxide and sodium bromide in an aqueous environment. [D] . Bennett, Stephanie M. 2010

机译：具有防污/防污性能的溶胶-凝胶衍生的干凝胶薄膜的合成和表征，以及在水环境中用于过氧化氢和溴化钠溴化的螯合亚硒酸盐催化剂的制备，固定化和评估。
6. Easy Preparation of (Diacetoxyiodo)arenes from Iodoarenes with Sodium Percarbonate as the Oxidant [O] . Agnieszka Zielinska, Lech Skulski 2002

机译：以过碳酸钠为氧化剂由碘芳烃轻松制备（二乙酰氧基碘）芳烃
7. One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the Oxidant [O] . Anna Kryska, Lech Skulski 2013

机译：来自Iodoarenes和arenes的二芳基碘化物的一锅法制备，以过硼酸钠为氧化剂

One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes with Sodium Perborate as the Oxidant†

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