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Novel 4-Aroyl-3-alkoxy-2(5H)-furanones as Precursors for the Preparation of Furo34-b14-diazepine Ring System‡

机译：新型4-芳基-3-烷氧基-2（5H）-呋喃酮类化合物可制备Furo 34-b 14-二氮杂Ring环系统

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摘要

A general synthesis of tetronic acid derivatives, namely 4-aroyl-3-alkoxy-2(5H)-furanones, is achieved via the treatment of an anhydrous dimethylformamide (DMF) solution of 4-aroyl-3-hydroxy-2(5H)-furanones with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as base at -10-0°C, followed by the addition of alkyl iodide. Their structural assignments are based on spectroscopic data and confirmed by X-ray crystallography. These furanones were used as starting materials for the preparation of furodiazepines.

机译：通过处理4-aroyl-3-hydroxy-2（5H）的无水二甲基甲酰胺（DMF）溶液，可以实现对tetronic酸衍生物（即4-aroyl-3-alkoxy-2（5H）-呋喃酮）的一般合成。在-10-0℃以1,8-二氮杂双环[5.4.0]十一碳-7-烯（DBU）为基的呋喃酮，然后加入烷基碘。它们的结构分配基于光谱数据，并通过X射线晶体学确认。这些呋喃酮被用作制备呋喃二氮杂类的原料。

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期刊名称 Molecules
作者
Hans Zimmer; Christian P. Librera; Sven Hausner; Jeanette Bauer; Adel Amer;
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作者单位

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年(卷),期 2003(8),10
年度 2003
页码 735–743
总页数 9
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
4-Aroyl-3-alkoxy-2(5H)-furanones 7-aryl-45-dihydro-2-oxo-3H 8H-furo-34-b14diazepines X-ray structures;

机译：4-芳基-3-烷氧基-2（5H）-呋喃酮;7-芳基-45-二氢-2-氧代-3H;8H-呋喃-34-b 14二氮杂 X射线结构;

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专利

1. Novel 4-Aroyl-3-alkoxy-2(5H)-furanones as Precursors for the Preparation of Furo[3,4-b][1,4]-diazepine Ring System‡ [J] . Adel Amer, Christian P. Librera, Hans Zimmer, Molecules . 2003,第10期

机译：新型4-芳基-3-烷氧基-2（5H）-呋喃酮类化合物可制备Furo [3,4-b] [1,4]-二氮杂苯环系统‡
2. BROMINATED ANALOGS OF 3-CHLORO-4-(DICHLOROMETHYL)-5-HYDROXY-2(5H)- FURANONE: PREPARATION OF 3-CHLORO-4-(BROMOCHLOROMETHYL)-5- HYDROXY-2(5H)-FURANONE AND MUTAGENICITY STUDIES [J] . Isabel Ramos, Maia Lloveras, Xavier Solans Environmental toxicology and chemistry . 2000,第11期

机译：3-氯-4-（二氯甲基）-5-羟基-2（5H）-呋喃酮的溴化类似物：3-氯-4-（溴代氯甲基）-5-羟基-2（5H）-呋喃酮的制备及突变研究
3. Mucochloric acid: a useful synthon for the selective synthesis of 4-aryl-3-chloro-2(5H)-furanones, (Z)-4-aryl-5-[1-(aryl)methylidene]-3-chloro-2(5H)-furanones and 3,4-diaryl-2(5H)-furanones [J] . Fabio Bellina, Chiara Anselmi, Francesca Martina, European journal of organic chemistry . 2003,第12期

机译：粘氯酸：有用的合成子，用于选择性合成4-芳基-3-氯-2（5H）-呋喃酮，（Z）-4-芳基-5- [1-（芳基）亚甲基] -3-氯-2 （5H）-呋喃酮和3,4-二芳基-2（5H）-呋喃酮
4. Pilot-plant study of the formaiton of the disinfection by-product 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) in dinking water [C] . C.J.Hwang, S.W.Krasner, S.A.Andrews, Ozonation for drinking water treatment . 1992

机译：在饮用水中形成消毒副产物3-氯-4-（氯甲基）-5-羟基-2（5H）-呋喃酮（MX）的中试研究
5. Removal of 3-chloro-4-dichloromethyl-5-hydroxy-2(5H)-furanone (MX) Precursors during Water Treatment Biofiltration [D] . Mian, Noreen 2018

机译：水处理生物过滤过程中去除3-氯-4-二氯甲基-5-羟基-2（5H）-呋喃酮（MX）前体
6. Preparation and Characterizationof Poly-123-triazolewith Chiral 2(5H)-Furanone Moiety as PotentialOptical Brightening Agents [O] . Jingpei Huo, *, ∥, 2017

机译：制备与表征123-三唑的合成以手性2（5H）-呋喃酮部分为潜能荧光增白剂
7. Novel 4-Aroyl-3-alkoxy-2(5H)-furanones as Precursors for the Preparation of Furo[3,4-b][1,4]-diazepine Ring System [O] . Adel Amer, Jeanette Bauer, Sven Hausner, 2003

机译：新型4-芳酰基-3-烷氧基-2（5H） - 呋喃酮作为前体制备Furo [3,4-b] [1,4] - 二氮杂环系统
8. Induction of Gastrointestinal Tract Nuclear Anomalies in B6C3F1 Mice by 3-Chloro-4-(Dichloromethyl)-5-Hydroxy-2(5H)-Furanone and 3,4-(Dichloro)-5-Hydroxy-2(5H)-Furanone, Mutagenic Byproducts of Chlorine Disinfection [R] . Daniel, F. B., Olson, G. R., Stober, J. A. 1991

机译：用3-氯-4-（二氯甲基）-5-羟基-2（5H） - 呋喃酮和3,4-（二氯）-5-羟基-2（5H） - 呋喃酮诱导B6C3F1小鼠胃肠道核异常，氯消毒的诱变副产物

Novel 4-Aroyl-3-alkoxy-2(5H)-furanones as Precursors for the Preparation of Furo34-b14-diazepine Ring System‡

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